Defination of Bleaching | Objects of Bleaching | Selection of bleaching agent | Classification of Bleaching agent | Factor of peroxide Bleaching | H2O2 is called Universal bleaching agent
Defination of Bleaching:
Bleaching is chemical treatment employed for the removal of
natural coloring matter from the substrate. The source of natural color is
organic compounds with conjugated double bonds , by doing chemical bleaching
the discoloration takes place by the breaking the chromophore , most likely
destroying the one or more double bonds with in this conjugated system. The
material appears whiter after the bleaching.
Objects of Bleaching:
- Removal of coloured impurities.
- Removal of the seed coats.
- Minimum tendering of fibre.
- Low chemical & energy consumption.
- Increasing the degree of whiteness.
Sodium hypo chloride
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H2O2
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||||
cellulose
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++
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++
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++
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++
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++
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Animal
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-
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-
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-
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++
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++
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Polyamide
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+
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++
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-
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(+)
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++
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Polyester
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(+)
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++
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+
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+
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+
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Polyacrylonitrile
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-
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++
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+
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(+)
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+
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++ ..............Process highly soluble.
+.................Process applicable without fiber damage but without achieving and whitening effect.
(+)................Process applicable only with special precaution.
- ...................Process Unsuitable
Classification of Bleaching agent:
Factor of peroxide Bleaching:
- Temperature:80-95 for cotton and Bust &75-80 for cellulose fibers
- Time:18-24 Hours
- pH:9-10
- Water Quality:Soft water
Why H2O2 is called Universal bleaching agent:
- Because it can be employed for bleaching fibers like wool,silk, and jute also.
- It requires less handling of fabric and hence less labor.
- The loss of weight in bleaching is less.
- Less water is required.
- More absorbent.
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