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Defination of Bleaching | Objects of Bleaching | Selection of bleaching agent | Classification of Bleaching agent | Factor of peroxide Bleaching | H2O2 is called Universal bleaching agent


Defination of Bleaching:

Bleaching is chemical treatment employed for the removal of natural coloring matter from the substrate. The source of natural color is organic compounds with conjugated double bonds , by doing chemical bleaching the discoloration takes place by the breaking the chromophore , most likely destroying the one or more double bonds with in this conjugated system. The material appears whiter after the bleaching.

Objects of Bleaching:

  • Removal of coloured impurities. 
  • Removal of the seed coats. 
  • Minimum tendering of fibre. 
  • Low chemical & energy consumption. 
  • Increasing the degree of whiteness.
Selection of bleaching agent according to fiber types:

 Type of Fiber
Alkali 
Sodium chloride 
Sodium hypo chloride
H2O2 
Reducing Agent 
cellulose
++
++
++
++
++
Animal
-
-
-
++
++
Polyamide
+
++
-
(+)
++
Polyester
(+)
++
+
+
+
Polyacrylonitrile
-
++
+
(+)
+
++ ..............Process highly soluble.
+.................Process applicable without fiber damage but without achieving and whitening effect.
(+)................Process applicable only with special precaution.
- ...................Process Unsuitable

Classification of Bleaching agent:


Factor of peroxide Bleaching:

  • Temperature:80-95 for cotton and Bust &75-80 for cellulose fibers 
  • Time:18-24 Hours
  • pH:9-10
  • Water Quality:Soft water

Why H2O2  is called Universal bleaching agent:
  • Because it can be employed for bleaching fibers like wool,silk, and jute also.
  • It requires less handling of fabric and hence less labor.
  • The loss of weight in bleaching is less.
  • Less water is required.
  • More absorbent.

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